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- W2023889213 abstract "Reaction of 1-diazo-3-trimethylsilylpropanone with olefins in the presence of cupric acetylacetonate (Cu(acac)2) affords cyclopropyl trimethylsilylmethyl ketones. One-flask procedure for the formation of these silylated ketones and subsequent treatment with organometallics or with lithium diisopropylamide (LDA) and then carbonyl compounds gives a variety of vinylcyclopropanes or cyclopropyl vinyl ketones in good yields, respectively. Cycloaddition of 1-diazo-3-trimethylsilylpropanone with acetylenes and similar carbon–carbon bond formation at the side chain of the cycloadducts lead to 3-pyrazolyl vinyl ketones." @default.
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- W2023889213 date "1986-09-01" @default.
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- W2023889213 title "Synthesis of Vinylcyclopropanes, Cyclopropyl Vinyl Ketones, and 3-Pyrazolyl Vinyl Ketones from 1-Diazo-3-trimethylsilylpropanone" @default.
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- W2023889213 doi "https://doi.org/10.1246/bcsj.59.2851" @default.
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