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- W2023892168 abstract "A two-step regiospecific synthesis of a new class of anionic and amphoteric methyl α-d-glucopyranoside-based surfactants is described. Reaction of methyl α-d-glucopyranoside with thionyl chloride followed by oxidation of the resulting sulfite afforded the corresponding methyl α-d-glucopyranoside 4,6-cyclic sulfate in high yield. Nucleophilic displacement of this cyclic sulfate by different fatty acids and amines led to the corresponding methyl 6-O-acyl- or 6-amino-6-deoxy-4-sulfoglucopyranosides in very good yields. These newly synthesized sulfoglucopyranoside-based surfactants displayed low critical micelle concentration (CMC) values." @default.
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- W2023892168 date "1999-04-01" @default.
- W2023892168 modified "2023-10-05" @default.
- W2023892168 title "Regiospecific Synthesis of New Methyl Sulfoglucopyranoside-Based Surfactants: Nucleophilic Displacement of a Cyclic Sulfate" @default.
- W2023892168 doi "https://doi.org/10.1055/s-1999-3432" @default.
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