Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023893633> ?p ?o ?g. }
- W2023893633 endingPage "11949" @default.
- W2023893633 startingPage "11942" @default.
- W2023893633 abstract "Oxime targeted reactions of the complexes trans-[(kappa(3)-dapdOH)Ru(CO)(PPh(3))(2)]PF(6) (1) (dapdOH = diacetylpyridinedioxime) and trans-[(kappa(3)-dapmOH)RuCl(PPh(3))(2)]PF(6) (2) (dapmOH = diacetylpyridinemonooxime) with SOCl(2), NaBH(4), or HCHO led into conversion of oxime to oximato, imino, or hydroxymethylimino groups. The reaction products have been characterized by analytical and spectral studies. Molecular structures of the representative homo/heteroleptic oxime/oximato complexes trans-[(kappa(3)-dapdOH)Ru(CO)(PPh(3))(2)]PF(6) (1), trans-[(kappa(3)-dapdO)Ru(CO)(PPh(3))(2)] (11) and oximato/imino complex trans-[(kappa(3)-dapd-NH)Ru(CO)(PPh(3))(2)]PF(6) (13) have been authenticated by single-crystal X-ray diffraction analyses. Structural studies revealed the presence of various oxime/oximato/imino based O-H...O, C-H...O, and N-H...F interactions in the complexes 1, 11, and 13." @default.
- W2023893633 created "2016-06-24" @default.
- W2023893633 creator A5006709098 @default.
- W2023893633 creator A5030108485 @default.
- W2023893633 creator A5034434638 @default.
- W2023893633 creator A5058490428 @default.
- W2023893633 creator A5064109029 @default.
- W2023893633 creator A5085601592 @default.
- W2023893633 date "2008-11-12" @default.
- W2023893633 modified "2023-10-16" @default.
- W2023893633 title "Reactivity of the Oxime/Oximato Group in Ruthenium(II) Complexes" @default.
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