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• W2023895022 abstract "X-ray absorption spectrum of cesium vapor in the K-edge region is measured in a stainless steel cell. The spectrum is free of the x-ray absorption fine structure signal and shows small features analogous to those in the spectrum of the neighbor noble gas Xe. Although the large natural width of the K vacancy $(>10mathrm{eV})$ washes out most of the details, fingerprints of multielectron excitations can be recognized at energies close to Dirac-Fock estimates of doubly excited states $1s4(d,p,s)$ and $1s3(d,p).$ Among these, the $1s3p$ excitation 1000 eV above the K edge in both spectra is the deepest double excitation observed so far. Within the K-edge profile, some resolution is recovered with numerical deconvolution of the spectra, revealing the coexcitation of the $5(p,s)$ electrons, and even the valence $6s$ electron in Cs. As in homologue elements, three-electron excitations, either as separate channels or as configuration admixtures are required to explain some spectral features in detail." @default.
• W2023895022 created "2016-06-24" @default.
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• W2023895022 date "2003-10-20" @default.
• W2023895022 modified "2023-09-23" @default.
• W2023895022 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>K</mml:mi></mml:math>-edge x-ray absorption spectra of Cs and Xe" @default.
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• W2023895022 doi "https://doi.org/10.1103/physreva.68.042505" @default.
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