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• W2023900417 abstract "Over the last decades, our understanding of σ-bond activation at transition metals has progressed considerably from both fundamental and synthetic points of view thanks to the preparation and characterization of a variety of σ complexes. Here we report the synthesis and structural analysis of the first σ complex involving a coinage metal. The copper(I) complex 2 derived from the diphosphine-disilane [Ph(2)P(C(6)H(4))Me(2)Si-SiMe(2)(C(6)H(4))PPh(2)] (1) has been isolated and crystallographically characterized. The coordination of the Si-Si σ bond to copper was thoroughly analyzed by quantum-chemical methods." @default.
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• W2023900417 date "2011-03-07" @default.
• W2023900417 modified "2023-10-07" @default.
• W2023900417 title "A Crystalline σ Complex of Copper" @default.
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• W2023900417 doi "https://doi.org/10.1021/ja200789z" @default.
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