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- W2023903676 abstract "Time-resolved hole-burning (HB) experiments have been performed on the S1 ← S0 0−0 transitions of free-base chlorin in polystyrene (H2Ch in PS) and bacteriochlorophyll-a in triethylamine (BChl-a in TEA) as a function of temperature (1.2–4.2 K), excitation wavelength, concentration, and delay time between burning and probing. At concentrations higher than 5 × 10−4M a new type of spectral diffusion process takes place, even at T → 0, which is induced by energy transfer. Moreover, HB-experiments on BChl-a in TEA with delay times between microseconds and hours at high (Δp ≈ 30 kbar) pressure demonstrate that a transition from a glassy- to a locally ordered structure occurs in this sample, suggesting that the number of “two-level-systems” in the glass responsible for spectral diffusion is reduced by compression." @default.
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- W2023903676 date "1995-12-01" @default.
- W2023903676 modified "2023-10-05" @default.
- W2023903676 title "Spectral diffusion induced by energy transfer and high-pressure effects in doped organic glasses: A hole-burning study" @default.
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- W2023903676 doi "https://doi.org/10.1016/0022-2313(95)00094-1" @default.
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