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• W2023921440 abstract "Chloride release from cis-PtCl2(NH3)2 dissolved in 0.1 M HClO4 is accelerated by the addition of either HgCl2 or Pb2+. Kinetic parameters associated with the second-order reactions are: kHgCl2 (25°C) =1.07×10−2 M−1 s−1, δH#=67.9 kJ mol−1 and δS#=−55 J K−1 mol−1, independent of [H+] (0.1–1.0 M) or ionic strength (0.1–1.0 M); kPb (25 °C)=3.72×10−4 M−1 s−1, δH#=85.5 kJ mol−1 and δS#=−24 J K−1 mol−1 (I=1.0 M). For Pb2+, the final product is cis-PtCl(NH3)2(OH2)+, but for HgCl2 the final products are cis-Pt(NH3)2(OH2)22+ and HgCl42− with this mixture forming crystals of cis-(PtCl2(NH3)2·(HgCl2)3)n at long reaction times. In this polymer (monoclinic, C2/c, a=18.532(5), b=6.506(2), c=12.492(4) Å, β=98.76(3)°, V=1485.5(8) Å3, Z=4, Dcalc=4.98 g/cc) each chloro ligand of the cis-PtCl2(NH3)2 unit is linked by PtClHg bridges to HgCl2 molecules to form a chain (Cl...Hg3.004(4) Å). An additional HgCl2 molecule is linked (Cl...Hg2.979(4) Å) to each of the bridging chloro ligands to give {PtCl2(NH3)2·(HgCl2)3]}n as the repeat unit." @default.
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• W2023921440 date "1991-06-01" @default.
• W2023921440 modified "2023-09-26" @default.
• W2023921440 title "The hydrolysis products of cis-diamminedichloroplatinum(II) 4. Metal ion assisted aquation of cis-PtCl2(NH3)2 and the structure of [cis-PtCl2(NH3)2·(HgCl2)3]n" @default.
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• W2023921440 doi "https://doi.org/10.1016/s0020-1693(00)83052-2" @default.
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