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- W2023924194 abstract "Although the complex-ions SeCl62−, SeBr62−, TeCl62− and TeBr62− are regular octahedral, the infrared spectra show that some evidence is present for vibronic coupling between ground state and first excited state (dynamic second order Jahn-Teller effect). The electronic absorption spectra are reported and assignments given. The splittings of the absorption bands closely resemble those found in the spectra of the alkali halide phosphors (KCl: Tl+ etc.). As for the phosphors, an explanation is given in terms of a dynamic Jahn-Teller effect in the excited states. In connection with this, attention is paid to the unusual intensities of the Jahn-Teller active modes (eg and t2g) in the Raman spectra of these complex-ions." @default.
- W2023924194 created "2016-06-24" @default.
- W2023924194 creator A5067584431 @default.
- W2023924194 date "2010-09-02" @default.
- W2023924194 modified "2023-10-17" @default.
- W2023924194 title "Dynamic Jahn-Teller effect in the excited states of SeCl62−, SeBr62−, TeCl62− and TeBr62−: Interpretation of electronic absorption and Raman spectra" @default.
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- W2023924194 doi "https://doi.org/10.1002/recl.19700891109" @default.
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