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- W2023930232 abstract "The reaction of the pentacarbonyl(diphenylcarbene) complexes (CO)5M[CPh2] (Ia: M = W; Ib: M = Cr) with trimethylsilylazide, Me3SiNNN, in dichloromethane affords benzophenoneimine(pentacarbonyl)-tungsten and -chromium, (CO)5M[N(H)=CPh2 (II), respectively, with evolution of N2. Complex Ia reacts with n-butylazide, BunNNN, to give (CO)5W[N(Bun)=CPh2] (III). The benzophenoneimine ligand in II and III is η1-bonded. The reactions correspond to formal insertion of “N-R” into the metal-carbene bond. Die Reaktion der Pentacarbonyl(diphenylcarben)-Komplexe (CO)5M[CPh2] (Ia: M = W; Ib: M = Cr) mit Trimethylsilylazid, Me3SiNNN, in Dichlormethan ergibt unter N2-Entwicklung Benzophenonimin(pentacarbonyl)-wolfram und -chrom, (CO)5M[N(H)=CPh2] (II). Mit n-Butylazid, BunNNN, reagiert la zu (CO)5W[C(Bun)=CPh2] (III). Der Benzophenoniminligand in II und III ist η1gebunden. Die Reaktionen entsprechen einer formalen Einschiebung von “N-R” in die Metall-Carbenkohlenstoff-Bindung." @default.
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- W2023930232 date "1985-05-01" @default.
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- W2023930232 title "Überführung eines carben- in einen benzophenonimin-liganden" @default.
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- W2023930232 doi "https://doi.org/10.1016/0022-328x(85)88006-2" @default.
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