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- W2023931182 abstract "Abstract Dimethylarsine reacts with (CH3)2AsCF2CCl CF2 to give the novel ligand 1,3-bis(dimethylarsino)-2-chloro-1,1,3,3,-tetrafluoropropane, (I). This ditertiary arsine affords the complexes (L-L)M(CO)4 and (L-L)Mn(CO)3,I (M = Cr, Mo; L-L = (I)), which contain six-membered chelate rings. The1H and19F NMR spectra have been studied in an attempt to obtain conformational information from the derived coupling constants. The19F spectra of the chromium and molybdenum complexes have been solved using spin “tickling” techniques." @default.
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- W2023931182 date "1974-01-01" @default.
- W2023931182 modified "2023-09-27" @default.
- W2023931182 title "Some NMR studies on six-membered chelate rings in fluorocarbon-bridged ditertiary arsine metal carbonyl complexes" @default.
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- W2023931182 doi "https://doi.org/10.1016/s0022-1139(00)82634-2" @default.
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