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• W2023931481 endingPage "5492" @default.
• W2023931481 startingPage "5492" @default.
• W2023931481 abstract "This work developed a novel ammonium oxalate–carbonate composite co-precipitation method to prepare spinel LiNi0.5Mn1.5O4. By this method combined with a facile hydrothermal treatment and particular cooling process, an ideal spinel with precise stoichiometric Ni/Mn and classic Fd3m structure is obtained, and furthermore, the Mn3+ content can be strictly limited. Additionally, the prepared LiNi0.5Mn1.5O4 has a spherical hierarchical morphology, composed of nano or submicron primary particles. This LiNi0.5Mn1.5O4 shows superlative electrochemical performance. It delivers a discharge capacity of 141.2 mA h g−1, and importantly 98.2% of which discharges at 4.7 V. After 200 cycles at 0.3 C, 1 C and 3 C, the capacity retentions are 96.3%, 94.4% and 91.1%, respectively. Chemical and electrochemical measurements indicate that the elimination of the majority of Mn3+ in the obtained LiNi0.5Mn1.5O4 results in the high capacity proportion at 4.7 V. Additionally, the retained Fd3m structure and spherical hierarchical morphology also effectively favour the cycling and rate performances." @default.
• W2023931481 created "2016-06-24" @default.
• W2023931481 creator A5019012748 @default.
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• W2023931481 date "2013-01-01" @default.
• W2023931481 modified "2023-09-25" @default.
• W2023931481 title "Precise preparation of high performance spherical hierarchical LiNi0.5Mn1.5O4 for 5 V lithium ion secondary batteries" @default.
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• W2023931481 doi "https://doi.org/10.1039/c3ta10980a" @default.
• W2023931481 hasPublicationYear "2013" @default.
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