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- W2023941719 abstract "syn-π-Crotylbis(triethyl phosphite) nickel hexafluorophosphate reacts with morpholine to give 1-(N-morpholino)-2-butene. This π-crotylnickel complex, without added acid, catalyzes the reaction of butadiene with morpholine. From these observations, π-allyl intermediates are proposed as intermediates in the amination of 1,3-dienes. trans-1,3-Pentadiene reacts with amines more easily than the cis-isomer. The different reactivities are discussed on the basis of the stability of π-allyl complexes which are assumed to be key intermediates." @default.
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- W2023941719 date "1974-09-01" @default.
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- W2023941719 title "Nickel-catalyzed amination of 1,3-dienes Evidence for a π-allyl intermediate" @default.
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- W2023941719 doi "https://doi.org/10.1016/s0022-328x(00)89428-0" @default.
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