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- W2023943941 abstract "A soft reduction: The new layered oxoferrate(II) SrFeO2 (see scheme: Fe red, Sr yellow, C gray) was synthesized by the reduction of the slightly oxygen-deficient perovskite SrFeO3−x at 400 K with CaH2 in a form of topotactical reaction. The square-planar-coordinated iron(II) ions in SrFeO2 exhibit a high-spin d6 configuration with a doubly occupied d orbital. SrFeO2 orders antiferromagnetically at an unusual high Néel temperature of TN=473 K." @default.
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- W2023943941 date "2008-06-02" @default.
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- W2023943941 title "Square-Planar Coordinated Iron in the Layered Oxoferrate(II) SrFeO2" @default.
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- W2023943941 doi "https://doi.org/10.1002/anie.200800855" @default.
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