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- W2023950892 abstract "A detailed examination is made of the morphologies and compositions of scales, formed by the reaction of Cu-Ni alloys with sulphur vapour, between 653 and 770 K, in order to examine factors which can lead to the formation of layered scales on alloys. The scales consist of several phases, each one essentially forming a discrete layer, although some second phase precipitation is observed in the inner nickel sulphides, which also contain ca. 1 wt%Cu in solution. The general order of phases is alloy/nickel sulphides/copper sulphides, the proportion of each sulphide varying with alloy composition. This sequence is the reverse of that expected from the relative thermodynamic stabilities of the copper and nickel sulphides. Possible reasons for this are discussed, and mechanisms leading to the formation of the observed layered morphology based on overgrowth phenomena and/or narrow alloy depletion and enrichment are outlined." @default.
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- W2023950892 date "1978-01-01" @default.
- W2023950892 modified "2023-10-14" @default.
- W2023950892 title "Sulphidation of copper-nickel alloys—I. Scale morphologies" @default.
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- W2023950892 doi "https://doi.org/10.1016/s0010-938x(78)80044-4" @default.
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