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- W2023952986 abstract "Aggregation behavior of bis-quaternary 1,4-diazabicyclo[2.2.2]octane derivatives of different hydrophobicity has been systematically investigated by tensiometry, potentiometry, spectrophotometry (dye solubilization), and fluorimetry of pyrene. The influence of structural and concentration factors on the critical micelle concentration, the concentration range of structural rearrangements of aggregates, the degree of counterion binding, the aggregation numbers, the Krafft temperature, the solubilization capacity of the micelles, and the parameters of adsorption of surfactants at the water–air interface was established. Bis-quaternary derivatives demonstrate higher critical micelle concentrations compared to monocationic analogs. Solubilization ability of dicationic surfactants is ca. 30 to 60% higher than that of acyclic counterparts and grows with the increase in the alkyl tail length. Morphological changes of aggregates at low surfactant concentrations (vesicle–micelle transition) were shown on the basis of dynamic light scattering and fluorimetry data using anisotropy probe. These findings demonstrate that the systems based on quaternary 1,4-diazabicyclo[2.2.2]octane derivatives can be recommended for further investigation as potential drug delivery systems." @default.
- W2023952986 created "2016-06-24" @default.
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- W2023952986 date "2015-10-01" @default.
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- W2023952986 title "Self-assembling systems based on diquaternized derivatives of 1,4-diazabicyclo[2.2.2]octane" @default.
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- W2023952986 doi "https://doi.org/10.1016/j.molliq.2015.01.018" @default.
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