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- W2023957802 abstract "The interaction of Y(III) and Ba(II) ions in the solid poly(vinyl alcohol) (PVA)-copper(II) acetate system with propionic acid was studied. Two kinds of coordination structures were detected in the films cast from an aqueous solution containing PVA and copper(II) acetate. One was a mononuclear Cu(II) complex, with the other being a binuclear Cu(II) complex of the cupric-acetate type. A significant decrease in the amounts of both of these complexes was observed on the addition of Y(III) and Ba(II) ions because of the formation of a multimetal polynuclear complex. The solubility of copper(II) acetate in aqueous PVA solution was increased by adding yttrium and barium acetates and attained its maximum level at a molar ratio of [Y]:[Ba]:[Cu] = 1:2:3. A precursor Y1Ba2Cu3Ox filament containing a large quantity of Y(III), Ba(II) and Cu(II) ions was shown to be beneficial for the generation of the superconducting phase by heat treatment." @default.
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- W2023957802 date "1996-03-01" @default.
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- W2023957802 title "Solution spinning of a high-Tc oxide superconductor: 5. The influence of yttrium and barium ions on the poly(vinyl alcohol)-copper(II) complex" @default.
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- W2023957802 doi "https://doi.org/10.1016/0032-3861(96)80831-7" @default.
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