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- W2023962870 abstract "Complexes of thorium(IV) and uranium(IV) trifluoro- and trichloro-acetates of the types M(O2CR)4·nL [n= 4, M = Th or U, L = CO(NHMe)2, R = CCl3 and M = Th, L = CO(NHMe)2, R = CF3; n= 3, M = Th or U, L = PMePh2O or PMe2PhO, R = CF3 or CCl3 and M = U, L = CO(NHMe)2, R = CF3; n= 2.5, M = Th or U, L = CO(NMe2)2, R = CCl3; n= 2, M = Th or U, L = CO(NMe2)2 R = CF3] have been prepared. The i.r. and u.v.–visible spectra [uranium(IV) complexes only] of these compounds are reported and the effects of steric crowding on the possible bonding arrangements of the carboxylate groups in the complexes are discussed in terms of a cone angle approach to steric crowding about the central metal ions." @default.
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- W2023962870 date "1984-01-01" @default.
- W2023962870 modified "2023-10-04" @default.
- W2023962870 title "Some urea and phosphine oxide complexes of thorium(IV) and uranium(IV) trihalogenoacetates" @default.
- W2023962870 doi "https://doi.org/10.1039/dt9840001527" @default.
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