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- W2023971325 abstract "Abinitio and INDO investigations of both the electronic structure and potential surfaces of various SiO2 molecular conformations and (SiO2)n (n = 2, 3, 4) molecular complexes have been carried out. The possibility of the formation of spatial structures resulting from the interaction of separate SiO2 molecules has been shown, the structures formed being similar to those existing in condensed forms of silicon dioxide. Starting from the concept of the formation of crystalline silicon dioxide structure and other silicates by consistent joining of separate SiO2 molecules, the explanation of the non-equivalent nature of the Si-O bonds in these compounds has been given. Two different mechanisms of switching these non-equivalent Si-O in silicates and the corresponding rearrangements of their structures and silification are also discussed." @default.
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- W2023971325 date "1986-01-01" @default.
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- W2023971325 title "On the nonequivalency of Si-O bonds in silicon dioxide" @default.
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- W2023971325 doi "https://doi.org/10.1016/0022-3697(86)90079-x" @default.
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