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- W2023985482 abstract "Abstract The binding of γ-picoline to horse heart ferricytochrome c(cyt c) by displacing methionine-80 has been studied using two dimensional exchange spectroscopy (EXSY) method. Some hyperfine shifted resonances arising from heme peripheral protons in the γ-picoline complex of cyt c(γ-MePy·cyt c) have been assigned. The rate and equilibrium constants of γ-picoline binding to cyt c have been measured and the thermodynamic values of ΔH°, ΔS° and the activation energy Ea for the forward reaction have been obtained. The patterns of the hyperfine shifts of γ-MePy·cyt c have been illustrated and the reason for the low affinity of γ-picoline to cyt c has been discussed." @default.
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- W2023985482 date "1998-06-01" @default.
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- W2023985482 title "2D Exsy Studies of γ-Picoline Binding to Cytochrome C" @default.
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- W2023985482 doi "https://doi.org/10.1080/00387019808007394" @default.
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