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- W2023986274 abstract "Abstract The adsorption of HCO 3 − ions was studied by a radiotracer method using 14 C labelled Na 2 CO 3 ( c ≤10 −2 mol dm −3 ) in the presence of a great excess of ClO 4 − ions (0.5 mol dm −3 NaClO 4 supporting electrolyte). A reversible adsorption of labelled species was found at pH values above 9. The voltammetric and differential voltradiometric behaviour of a Pt electrode in labelled carbonate solution shows a parallelism indicating the adsorption competition between hydrogen and carbonate species. Increasing the pH of the solution leads to a significant decrease in the extent of the adsorption of the labelled species. This phenomenon can be explained either by the transformation of adsorbing HCO 3 − into non-adsorbing CO 3 2− molecules or by the increasing role of the competitive adsorption of OH − ions at higher OH − concentrations. At pH values lower than 9 the slow strong chemisorption reported in the literature can be easily followed by the radiotracer technique." @default.
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- W2023986274 date "1998-08-01" @default.
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- W2023986274 title "Radiotracer study of the specific adsorption of HCO3− ions on a platinum electrode" @default.
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- W2023986274 doi "https://doi.org/10.1016/s0022-0728(98)00176-4" @default.
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