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• W2023987274 abstract "Understanding shape control during wet chemical synthesis is important for rational synthesis of nanostructures. Here, we show that two-dimensional metal structures can be obtained from metal salts by reducing the driving force of the reduction reaction that directly translates to the growth of the metal taking place by the two-dimensional nucleation (layer-by-layer growth) mechanism. Experimental evidence is provided for Au, Ag, Pt and Pd systems by choosing appropriate reaction conditions without using any external surfactant. The results are analyzed in terms of the calculations of driving force under different conditions. The results show that surfactants may not be important for producing shape control for the case of 2-D structures while they are required to obtain size control. It is shown that the regime of low driving force is also one where the kinetics of the process is slow and thus a new interpretation of the kinetic control hypothesis is provided." @default.
• W2023987274 created "2016-06-24" @default.
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• W2023987274 date "2009-02-01" @default.
• W2023987274 modified "2023-10-16" @default.
• W2023987274 title "Formation of two-dimensional structures by tuning the driving force of chemical reactions: An interpretation of kinetic control" @default.
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• W2023987274 doi "https://doi.org/10.1016/j.jcis.2008.10.027" @default.
• W2023987274 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18973903" @default.
• W2023987274 hasPublicationYear "2009" @default.
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