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- W2023990416 abstract "Crystalline Ni3B with a fused porous nanoparticle network has been synthesized directly in solution using a modified polyol method. KBH4 serves both as a reducing agent for Ni2+ and as a boron source, while tetraethylene glycol serves as a solvent capable of achieving reaction temperatures that can crystallize Ni3B. The reaction pathway was studied using X-ray diffraction, transmission electron microscopy, and electron diffraction, and a nucleation−aggregation−smoothing mechanism is proposed. Amorphous Ni−B alloy nanoparticles form first and then aggregate into larger networks, which crystallize and smooth to form porous crystalline Ni3B nanoparticle networks. Structural characterization by X-ray diffraction indicates that the lattice constants for nanocrystalline Ni3B are shifted relative to single-crystal Ni3B, likely because of some carbon incorporation based on X-ray photoelectron spectroscopy data. Magnetic measurements suggest the formation of a small amount of nanocrystalline Ni, which provides further insight into the reaction pathway. Scanning electron microscopy and Brunauer−Emmett−Teller surface area measurements indicate a porous morphology, and thermal analysis shows that boronized nickel generated from Ni3B is more resistant to oxidation than a similar sample of pure Ni." @default.
- W2023990416 created "2016-06-24" @default.
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- W2023990416 date "2008-11-19" @default.
- W2023990416 modified "2023-10-16" @default.
- W2023990416 title "Direct Solution Synthesis, Reaction Pathway Studies, and Structural Characterization of Crystalline Ni<sub>3</sub>B Nanoparticles" @default.
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- W2023990416 doi "https://doi.org/10.1021/jp8082503" @default.
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