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- W2023996308 abstract "Abstract Peptidolipin NA is a natural macrocyclic lactone constituted by a cyclic heptapeptide linked to a hydrophobic hydrocarbon chain. Its properties were investigated in chloroform by using 400 MHz 1 H NMR. In this solvent, δ NH , Δδ NH ΔT and 3 J NHCH of several residues depend on concentration, which reveals a self association process. The results agree with a rigid γ-turn in the L-Pro-D-aIle sequence, stabilized by a supplementary hydrogen bond involving the D-Ala NH group. The rest of the peptide cycle is more flexible and participates to intermolecular interactions especially through the L-Val residue." @default.
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- W2023996308 date "1980-06-01" @default.
- W2023996308 modified "2023-09-26" @default.
- W2023996308 title "A 400 MHz 1H NMR study of peptidolipin NA, a natural cyclic lipopeptide" @default.
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- W2023996308 doi "https://doi.org/10.1016/0006-291x(80)90562-8" @default.
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