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• W2024005983 startingPage "5131" @default.
• W2024005983 abstract "The development of cobalt(II) phthalocyanine–cobalt(II) tetra(5-phenoxy-10,15,20-triphenylporphyrin), (CoPc–(CoTPP)4) pentamer as a novel redox mediator for amperometric enzyme electrode sensitive to glucose is described. A glassy carbon electrode (GCE) was first modified with the pentamer, then followed by the immobilization onto the GCE–CoPc–(CoTPP)4 with glucose oxidase (GOx) through cross-linking with glutaraldehyde in the presence of bovine serum albumin (BSA) and Nafion® cation-exchange polymer. The proposed biosensor displayed good amperometric respose charateristics to glucose in pH 7.0 PBS solution; such as low overpotentials (+400 mV versus Ag|AgCl), very fast amperometric response time (∼5 s), linear concentration range extended up to 11 mM, with 10 μM detection limit. The biosensor exhibited electrochemical Michaelis–Menten kinetics and showed an average apparent Michaelis–Menten constant (K′M) of 14.91 ± 0.46 mM over a storage period of 2 weeks." @default.
• W2024005983 created "2016-06-24" @default.
• W2024005983 creator A5003290469 @default.
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• W2024005983 date "2006-07-01" @default.
• W2024005983 modified "2023-10-14" @default.
• W2024005983 title "Novel amperometric glucose biosensor based on an ether-linked cobalt(II) phthalocyanine–cobalt(II) tetraphenylporphyrin pentamer as a redox mediator" @default.
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• W2024005983 doi "https://doi.org/10.1016/j.electacta.2006.03.055" @default.
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