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- W2024013516 abstract "The synthesis of 6-benzyloxycarbonyl-1-oxa-6-azaspiro[4.5]decane-2-one 7a and 6-benzyloxycarbonyl-1,6-diazaspiro[4.5]decane-2-one 7b from (D,L)-pipecolinic acid is described. The extremely clean decarbonylation of the α-substituted amino acid 9d promoted by diphenylphosphorazidate (DPPA) is the key step of our strategy. The total synthesis of (±)-δ-coniceine (16) from the enamine ester 10a has been successfully achieved." @default.
- W2024013516 created "2016-06-24" @default.
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- W2024013516 date "1994-06-01" @default.
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- W2024013516 title "DPPA-Promoted decarbonylation of a N-Cbz-(D,L)-Pipecolinic acid derivative: An easy entry to [4.5]spirolactams and [4.5]spirolactones. Total synthesis of (±)-δ-coniceine" @default.
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- W2024013516 doi "https://doi.org/10.1016/s0040-4039(00)73161-3" @default.
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