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• W2024018430 abstract "The structure of 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C(4)mpyr][NTf(2)]) room-temperature ionic liquid at an electrified gold interface was studied using neutron reflectometry, cyclic voltammetry, and differential capacitance measurements. Subtle differences were observed between the reflectivity data collected on a gold electrode at three different applied potentials. Detailed analysis of the fitted reflectivity data reveals an excess of [C(4)mpyr](+) at the interface, with the amount decreasing at increasingly positive potentials. A cation rich interface was found even at a positively charged electrode, which indicates a nonelectrostatic (specific) adsorption of [C(4)mpyr](+) onto the gold electrode." @default.
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• W2024018430 date "2012-05-01" @default.
• W2024018430 modified "2023-10-09" @default.
• W2024018430 title "Structure of [C₄mpyr][NTf₂] Room-Temperature Ionic Liquid at Charged Gold Interfaces" @default.
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• W2024018430 doi "https://doi.org/10.1021/la3005757" @default.
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