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• W2024021207 abstract "Auger electron spectra have been recorded when oxygen is adsorbed on a Ni(111) single crystal surface. For the coverage range θ < 1, an analysis of the plot of the peak to peak height (H) of the oxygen KVV (516 eV) transition versus the total number of molecules cm2− impinging on the surface (molecular beam dosing) shows agreement with the kinetic mechanism proposed by Morgan and King [Surface Sci. 23 (1970) 259] for the adsorption of oxygen on polycrystalline nickel films. In this coverage range, no energy shifts of the nickel or oxygen Auger peaks were recorded. At coverages θ > 1 (standard dosing procedure) shifts in the valence spectra M2, 3VV (61 eV) and L3M2, 3V (782 eV) of −2.3 eV and −1.8eV respectively are recorded at 1.4 × 10−2 torr-sec. Up to these coverages no shift of the L3VV transition (849 eV) is observed. A chemical shift of −2.1 eV is recorded in the L3M2, 3M2, 3 Auger transition (716 eV) at 1.4 × 10−2 torr-sec. In the coverage range θ > 1, shifts in the energy of the oxygen Auger peaks are observed. At 5.8 × 10−3 torr-sec. the KVV (516 eV) and KL1V (495.2 ± 0.3 eV) transitions show shifts of −1.5 eV and −(1.0 ±0.3) eV respectively. No shift up to this coverage is recorded in the KL1L1 (480.6 ± 0.3 eV) transition." @default.
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• W2024021207 date "1973-05-01" @default.
• W2024021207 modified "2023-10-18" @default.
• W2024021207 title "A study of the adsorption of oxygen on Ni(111) using auger electron spectroscopy: Chemical shifts and valence spectra" @default.
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• W2024021207 doi "https://doi.org/10.1016/0039-6028(73)90400-7" @default.
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