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- W2024026069 abstract "The electron paramagnetic resonance spectra of Cu2+ in an Na3PO4·8H2O single crystal were studied at room temperature. The spectra indicate the presence of two magnetically inequivalent sites and monoclinic symmetry of the crystal. The principal values of the g and the hyperfine tensors were determined and were found to be in agreement with the literature values. It is proposed that the Cu2+ ions replace the Na+ ions, and the charge compensation is fulfilled by the charge of a nearby proton vacancy of the coordinating water molecules. The ground state wavefunction of the Cu2+ is thought to be an admixture of the 3dx2−y2 and 3dz2 orbitals and the admixtures of the two magnetically inequivalent sites were obtained." @default.
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- W2024026069 date "2001-07-01" @default.
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- W2024026069 title "Electron paramagnetic resonance of Cu2+ in Na3PO4·8H2O single crystal" @default.
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- W2024026069 doi "https://doi.org/10.1016/s1466-6049(01)00017-4" @default.
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