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- W2024034426 endingPage "2105" @default.
- W2024034426 startingPage "2092" @default.
- W2024034426 abstract "Amphiphilic linear ternary block copolymers (ABC) were synthesized in three consecutive steps by the reversible addition−fragmentation chain transfer (RAFT) method. Using oligo(ethylene oxide) monomethyl ether acrylate, benzyl acrylate, and 1H,1H-perfluorobutyl acrylate monomers, the triblock copolymers consist of a hydrophilic (A), a lipophilic (B), and a fluorophilic (C) block. The block sequence of the triphilic copolymers was varied systematically to provide all possible variations: ABC, ACB, and BAC. All blocks have glass transition temperatures below 0 °C. Self-assembly into spherical micellar aggregates was observed in aqueous solution, where hydrophobic cores undergo local phase separation into various ultrastructures as shown by cryogenic transmission electron microscopy (cryo-TEM). Selective solubilization of substantial quantities of hydrocarbon and fluorocarbon low molar mass compounds by the lipophilic and fluorophilic block, respectively, is demonstrated." @default.
- W2024034426 created "2016-06-24" @default.
- W2024034426 creator A5024247648 @default.
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- W2024034426 creator A5060772989 @default.
- W2024034426 creator A5070951769 @default.
- W2024034426 creator A5082911307 @default.
- W2024034426 date "2011-03-02" @default.
- W2024034426 modified "2023-09-23" @default.
- W2024034426 title "Self-Assembly into Multicompartment Micelles and Selective Solubilization by Hydrophilic−Lipophilic−Fluorophilic Block Copolymers" @default.
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- W2024034426 doi "https://doi.org/10.1021/ma200032j" @default.
- W2024034426 hasPublicationYear "2011" @default.
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