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- W2024061878 abstract "Abstract Mononuclear palladium(II) complexes of the type [Pd(Epy)(S∩S)(PPh3)] [E=S or Se; S∩S=S2CNEt2, S2P(OR)2 (R=Et, Prn, Pri)] have been prepared. All the complexes have been characterized by elemental analysis and NMR (1H, 31P{1H}, 77Se{1H}) spectral data. The NMR data indicate that there are two species in solution, i.e. one with chelating S∩S ligand predominates (∼95%) while the other with chelating Epy and monodentate S∩S existing in ∼5% concentration. The X-ray crystal structure of [Pd(Spy){S2P(OPri)2}(PPh3)] has been determined. The square planar palladium atom is coordinated to asymmetrically chelated (PriO)2PS2− ligand, PPh3 and pyS− groups." @default.
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- W2024061878 date "1999-03-01" @default.
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- W2024061878 title "Synthesis and characterization of monomeric palladium(II) pyridine-2-chalcogenolate complexes" @default.
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- W2024061878 doi "https://doi.org/10.1016/s0277-5387(98)00426-4" @default.
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