FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024073431> ?p ?o ?g. }

• W2024073431 endingPage "734" @default.
• W2024073431 startingPage "723" @default.
• W2024073431 abstract "The reaction of the digold(I) diacetylide [(AuCCCH2OC6H4)2CMe2] with diphosphane ligands can lead to formation of either macrocyclic ring complexes or [2]catenanes by self-assembly. This gives an easy route to rare organometallic [2]catenanes, and the effect of the diphosphane ligand on the selectivity of self-assembly is studied. With diphosphane ligands Ph2P(CH2)xPPh2, the simple ring complex [Au2[(CCCH2OC6H4)2CMe2](Ph2P(CH2)xPPh2)] is formed selectively when x = 2, but the [2]catenanes [Au2[(CCCH2OC6H4)2CMe2](Ph2P(CH2)xPPh2)]2 are formed when x = 4 or 5. When x = 3, a mixture of the simple ring and [2]catenane is formed, along with the double-ring complex, [Au4[(CCCH2OC6H4)2CMe2]2(Ph2P(CH2)3PPh2)2] and a hexamer Au2[(CCCH2OC6H4)2CMe2](Ph2P(CH2)3PPh2)]6] whose structure is not determined. A study of the equilibria between these complexes by solution NMR techniques gives insight into the energetics and mechanism of [2]catenane formation. When the oligomer [(AuCCCH2OC6H4)2CMe2] was treated with a mixture of two diphosphane ligands, or when two [2]catenane complexes [[Au2[(CCCH2OC6H4)2CMe2](diphosphane)]2] were allowed to equilibrate, only the symmetrical [2]catenanes were formed. The diphosphanes Ph2PCCPPh2, trans-[Ph2PCH=CHPPh2] and (Ph2PC5H4)2Fe give the corresponding ring complexes [Au2[(CCCH2OC6H4)2CMe2](diphosphane)], and the chiral, unsymmetrical diacetylide [Au2[(CCCH2OC6H4C(Me)(CH2CMe2)C6H3OCH2CC)] gives macrocyclic ring complexes with all diphosphane ligands Ph2P(CH2)xPPh2 (x = 2-5)." @default.
• W2024073431 created "2016-06-24" @default.
• W2024073431 creator A5012804768 @default.
• W2024073431 creator A5021402070 @default.
• W2024073431 creator A5026694705 @default.
• W2024073431 creator A5033575784 @default.
• W2024073431 creator A5073410834 @default.
• W2024073431 date "2002-02-01" @default.
• W2024073431 modified "2023-10-16" @default.
• W2024073431 title "Self-Assembly of Gold(I) Rings and Reversible Formation of Organometallic [2]Catenanes" @default.
• W2024073431 cites W135787191 @default.
• W2024073431 cites W1511711056 @default.
• W2024073431 cites W1544546998 @default.
• W2024073431 cites W158347052 @default.
• W2024073431 cites W1925105860 @default.
• W2024073431 cites W1964824663 @default.
• W2024073431 cites W1965272987 @default.
• W2024073431 cites W1966545431 @default.
• W2024073431 cites W1969885133 @default.
• W2024073431 cites W1971597127 @default.
• W2024073431 cites W1978659336 @default.
• W2024073431 cites W1984284687 @default.
• W2024073431 cites W1985901667 @default.
• W2024073431 cites W1988502687 @default.
• W2024073431 cites W1988789838 @default.
• W2024073431 cites W1992980543 @default.
• W2024073431 cites W1995552037 @default.
• W2024073431 cites W1998651457 @default.
• W2024073431 cites W2007057140 @default.
• W2024073431 cites W2007598040 @default.
• W2024073431 cites W2007639251 @default.
• W2024073431 cites W2012815053 @default.
• W2024073431 cites W2015715149 @default.
• W2024073431 cites W2018689105 @default.
• W2024073431 cites W2019626206 @default.
• W2024073431 cites W2022077257 @default.
• W2024073431 cites W2026273666 @default.
• W2024073431 cites W2038608101 @default.
• W2024073431 cites W2049650033 @default.
• W2024073431 cites W2051178859 @default.
• W2024073431 cites W2052265901 @default.
• W2024073431 cites W2057834109 @default.
• W2024073431 cites W2065273366 @default.
• W2024073431 cites W2066696332 @default.
• W2024073431 cites W2074486379 @default.
• W2024073431 cites W2075173954 @default.
• W2024073431 cites W2075588831 @default.
• W2024073431 cites W2075745859 @default.
• W2024073431 cites W2079994025 @default.
• W2024073431 cites W2081684485 @default.
• W2024073431 cites W2083546295 @default.
• W2024073431 cites W2090438988 @default.
• W2024073431 cites W2094682831 @default.
• W2024073431 cites W2100814843 @default.
• W2024073431 cites W2102133522 @default.
• W2024073431 cites W2117041482 @default.
• W2024073431 cites W2122220082 @default.
• W2024073431 cites W2124963706 @default.
• W2024073431 cites W2131414053 @default.
• W2024073431 cites W2144087168 @default.
• W2024073431 cites W2164621431 @default.
• W2024073431 cites W2166042610 @default.
• W2024073431 cites W2331557911 @default.
• W2024073431 cites W2950533837 @default.
• W2024073431 cites W4205744890 @default.
• W2024073431 cites W4211103670 @default.
• W2024073431 cites W4211186777 @default.
• W2024073431 cites W4235954120 @default.
• W2024073431 cites W4254180029 @default.
• W2024073431 cites W4254527655 @default.
• W2024073431 doi "https://doi.org/10.1002/1521-3765(20020201)8:3<723::aid-chem723>3.0.co;2-t" @default.
• W2024073431 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11855720" @default.
• W2024073431 hasPublicationYear "2002" @default.
• W2024073431 type Work @default.
• W2024073431 sameAs 2024073431 @default.
• W2024073431 citedByCount "67" @default.
• W2024073431 countsByYear W20240734312012 @default.
• W2024073431 countsByYear W20240734312013 @default.
• W2024073431 countsByYear W20240734312014 @default.
• W2024073431 countsByYear W20240734312015 @default.
• W2024073431 countsByYear W20240734312016 @default.
• W2024073431 countsByYear W20240734312017 @default.
• W2024073431 countsByYear W20240734312019 @default.
• W2024073431 countsByYear W20240734312020 @default.
• W2024073431 crossrefType "journal-article" @default.
• W2024073431 hasAuthorship W2024073431A5012804768 @default.
• W2024073431 hasAuthorship W2024073431A5021402070 @default.
• W2024073431 hasAuthorship W2024073431A5026694705 @default.
• W2024073431 hasAuthorship W2024073431A5033575784 @default.
• W2024073431 hasAuthorship W2024073431A5073410834 @default.
• W2024073431 hasConcept C178790620 @default.
• W2024073431 hasConcept C185592680 @default.
• W2024073431 hasConcept C2780378348 @default.
• W2024073431 hasConcept C32909587 @default.
• W2024073431 hasConcept C50837382 @default.
• W2024073431 hasConcept C71240020 @default.
• W2024073431 hasConcept C8010536 @default.
• W2024073431 hasConceptScore W2024073431C178790620 @default.

• next