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• W2024078246 abstract "The compounds bis(phenylmethyl) cis-cyclobutene-3,4-dicarboxylate (1) and cis-3,4-bis(2-oxa-3-phenylpropyl)cyclobutene (2) were polymerized by ring-opening metathesis polymerizations using Mo(CHC(CH3)2R1)(NC6H3-2,6-diisopropyl)(OR2)2 (R1 = Ph, R2 = C(CH3)3, I; R1 = CH3, R2 = C(CF3)2CH3, II) as the initiator. For I as initiator, no chain termination or chain transfer processes were observed during the lifetime of the polymerization, showing that the polymerizations of 1 and 2 by I are living. Block copolymers containing 1 and 2 and diethyl cis-cyclobutene-3,4-dicarboxylate (5) were synthesized. The double bonds of the poly-2 and poly-3 ranged from 70% trans to 92% cis depending on the initiator and monomer used. Poly-1 and poly-2 were treated with iodotrimethylsilane and converted to the acid-functionalized and alcohol-functionalized poly-4 and poly-6, respectively. Block copolymers were treated with iodotrimethylsilane and converted to materials with blocks bearing protic functionalities and blocks bearing polar aprotic groups." @default.
• W2024078246 created "2016-06-24" @default.
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• W2024078246 date "1996-01-01" @default.
• W2024078246 modified "2023-10-14" @default.
• W2024078246 title "Living Ring-Opening Metathesis Polymerizations of 3,4-Disubstituted Cyclobutenes and Synthesis of Polybutadienes with Protic Functionalities" @default.
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• W2024078246 doi "https://doi.org/10.1021/ma951516j" @default.
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