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- W2024088950 abstract "Abstract Redox-initiated free-radical cyclopolymerization of the nonconjugated divinyl monomer N,N′-methylenebisacrylamide was studied at 25–40°C, involving trisacetatomanganese(III) dihydrate as oxidant with four different reductants, methyl ethyl ketone (2-butanone), cyanoacetic acid, malic acid, and thiomalic acid. While the general mechanistic sequence is the same, the modes of termination are different in these cases. Because the reactivities of the different free radicals from the four redox pairs are different, the kinetic order with respect to the monomer, oxidant, and reductant differ considerably in magnitude. The kinetic and thermodynamic parameters were calculated." @default.
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- W2024088950 date "1988-08-01" @default.
- W2024088950 modified "2023-09-26" @default.
- W2024088950 title "Kinetics of Cyclopolymerization ofN,N′-Methylenebisacrylamide Initiated by Redox Couples with Mn(III). Part III" @default.
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- W2024088950 doi "https://doi.org/10.1080/00222338808052132" @default.
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