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• W2024093051 endingPage "16133" @default.
• W2024093051 startingPage "16132" @default.
• W2024093051 abstract "An enantioselective nucleophilic substitution reaction of achiral dialkoxysilane has been developed. The reaction proceeds with efficient stereocontrol on the silicon chirality center to give the enantioenriched silyl ether, which can be converted to the silanol without loss of enantiopurity. We have analyzed the steric course of the reaction by using DFT calculations and propose a transition state model to explain the observed enantioselectivity." @default.
• W2024093051 created "2016-06-24" @default.
• W2024093051 creator A5055743193 @default.
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• W2024093051 date "2008-11-11" @default.
• W2024093051 modified "2023-10-02" @default.
• W2024093051 title "Enantioselective Synthesis of Silanol" @default.
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• W2024093051 doi "https://doi.org/10.1021/ja805848z" @default.
• W2024093051 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18998686" @default.
• W2024093051 hasPublicationYear "2008" @default.
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