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- W2024098846 abstract "The quasi-elastic light-scattering (homodyne) time-correlation functions of calf thymus and λDNA are shown to contain contributions from at least two relaxation processes. A method of asymptotic analysis is described and used to obtain an estimate of the longest relaxation time as well as the “average” relaxation time and the mean-squared dispersion in this average. Most theories of scattering from macromolecules in the limit of inifinite dilution predict that the longest relaxation time is due to translational self-diffusion. The data obtained, however, indicate that the longest time is not simply related to the translational self-diffusion coefficient of unaggregated macromolecules. It is also shown that the longest relaxation time of λDNA decreases in the later stages of the denaturation transition region. Some possible mechanisms for the origin of this long time are discussed, including a model of restricted motion of a molecule by its neighbors." @default.
- W2024098846 created "2016-06-24" @default.
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- W2024098846 date "1975-03-01" @default.
- W2024098846 modified "2023-10-16" @default.
- W2024098846 title "Quasi-elastic light scattering by calf thymus DNA and ?DNA" @default.
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- W2024098846 doi "https://doi.org/10.1002/bip.1975.360140308" @default.
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