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• W2024105272 abstract "Enantiomeric separation of racemic mexiletine hydrochloride was performed using cyclodextrins (CDs) including α-CD, β-CD, heptakis-2,6-di-O-methyl-β-CD (DM-β-CD), heptakis-2,3,6-tri-O-methyl-β-CD (TM-β-CD), 2-O-(2-hydroxypropyl)-β-CD and γ-CD as chiral selectors. However, the enantiomers can be chirally separated only by methyl-β-CDs. The enantiomers could be baseline separated when TM-β-CD was used, and were only partially separated by DM-β-CD and no chiral separation was obtained using β-CD; thus, it is believed that methoxy groups of methyl-β-CDs play a key role in the chiral recognition for racemic mexiletine. Effects of CD concentration, applied voltage and the organic additive on chiral separation were studied. Under the conditions of 40 mmol/l Tris–H3PO4 buffer at pH 2.5 containing 20 mmol/l TM-β-CD, baseline separation (Rs=2.3) of the enantiomers can be achieved." @default.
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• W2024105272 date "1998-02-01" @default.
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• W2024105272 title "Chiral separation of racemic mexiletine hydrochloride using cyclodextrins as chiral additive by capillary electrophoresis" @default.
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• W2024105272 doi "https://doi.org/10.1016/s0021-9673(97)00974-6" @default.
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