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- W2024128255 abstract "Phosphate glasses are promising materials for electrolytes of intermediate temperature fuel cells, because they have good proton conductivity at 150–250 °C. However, the effects of the glass composition and melting condition on proton conductivities are unclear yet. In this work, the structures of BaO–ZnO–P2O5 glasses were investigated by magic angle spinning-nuclear magnetic resonance (MAS-NMR) and Raman spectroscopy, and the proton conductivities were measured by an AC impedance method. The proton conductivity of 30 mol%ZnO-70 mol%P2O5 glass melted at 800 °C reached 1 × 10−3 S/cm at 250 °C for. The proton transportation number of the ZnO–P2O5 glass was almost unity, confirmed by a hydrogen concentration cell. The power density of 0.4 mW/cm2 was obtained for a fuel cell using the ZnO–P2O5 glass electrolyte at 250 °C. A branching phosphate structure was transformed into a middle phosphate structure by substituting BaO with ZnO, which caused an improvement in proton mobility." @default.
- W2024128255 created "2016-06-24" @default.
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- W2024128255 date "2013-11-01" @default.
- W2024128255 modified "2023-09-23" @default.
- W2024128255 title "Proton conductivities and structures of BaO–ZnO–P2O5 glasses in the ultraphosphate region for intermediate temperature fuel cells" @default.
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- W2024128255 doi "https://doi.org/10.1016/j.ijhydene.2013.09.087" @default.
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