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- W2024130014 abstract "A practical synthesis of (2S,3aS,4aS)-2-tert-butyldimethylsilyloxybicyclo[3.1.0]hexane-3a-carbaldehyde (14a) and diastereoisomers, starting from all-cis methyl 3,5-dihydroxy-1cyclohexanecarboxylate (24) is described. Coupling with appropriate cis-hydrindanes produces the title compounds. TX 522, a member of this series, is currently in phase II clinical studies for the treatment of psoriasis. The key step involves the coupling of 14 and 16 with the respective cis-hydrindanes 9 and 7." @default.
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- W2024130014 date "2001-10-01" @default.
- W2024130014 modified "2023-09-27" @default.
- W2024130014 title "A Practical Synthesis of 14-epi-19-nor-1α,25-Dihydroxyvitamin D3 Analogues and Their A-ring Epimers" @default.
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- W2024130014 doi "https://doi.org/10.1002/1099-0690(200110)2001:20<3779::aid-ejoc3779>3.0.co;2-q" @default.
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