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- W2024131462 abstract "Reaction of the labile clusters Os3(CO)11(NCME) (1) with primary arsines (RAsH2; R = Ph, Me, H) yields the arsinidene compounds H2Os2(CO)11(μ3-AsR) (2a: R = Ph; 2b: R = Me; 2c: R = H) in which the cluster framework consists of an HOs(CO)4 and an HOs2(CO)7 unit linked together by a μ3-AsR group. The 1H NMR spectra of 2a2c reveal the presence of two isomers in each case. At elevated temperatures, 2a can be transformed to the AsPh capped cluster (μ-H)2Os3(OC)9-(μ3-AsPh) (3). Treatment of the phenyl derivative 2a with Os sources such as Os3(CO)12, H2Os2(CO)10, or H2OS(CO)4 gives, under thermolytic conditions, the tetranuclear cluster (μ-H)2Os4(CO)12(μ3-AsPh) (4) and the pentanuclear cluster Os5(CO)15(μ4-AsPH) (5)." @default.
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- W2024131462 date "1988-11-01" @default.
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- W2024131462 title "Cluster build up with arsinidene ligands: synthesis and characterization of some RAs-bridged tri-, tetra- and penta-nuclear osmium carbonyl clusters" @default.
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- W2024131462 doi "https://doi.org/10.1016/0022-328x(88)89041-7" @default.
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