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• W2024131870 endingPage "161" @default.
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• W2024131870 abstract "The crystal and molecular structures of the ternary copper–indomethacin complexes [Cu2(Indo)4L2] (IndoH=indomethacin=1-(4-chlorobenzoyl)-5-methoxy-2-methyl-1H-indole-3-acetic acid; L=acetonitrile (AN), N,N-dimethylacetamide (DMA), tetrahydrofuran (THF), or pyridine (Py)) are reported. All four complexes contain a dinuclear ‘Cu-acetate’ molecular structure in which the carboxyl groups of the indomethacin ligands act as bridges. The CuCu distances of 2.649(3), 2.6240(8), and 2.6784(8) Å; CuO(Ac)av distances of 1.964, 1.970, and 1.967 Å; and CuL distances of 2.132(6), 2.1805(17), and 2.177(2) Å, respectively, for L=DMA, THF and Py, are typical of such distances in dinuclear complexes of this type. There are two independent complexes in the AN adduct with CuCu distances of 2.6311(11) and 2.6206(8) Å; CuO(Ac)av distances of 1.965 and 1.965 Å; and CuLav distances of 2.184 and 2.197 Å, respectively. The pyridine complex exists mainly as a monomer in solution, which may be associated with the longer CuCu bond in this adduct as compared to the other complexes." @default.
• W2024131870 created "2016-06-24" @default.
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• W2024131870 date "2001-11-01" @default.
• W2024131870 modified "2023-10-02" @default.
• W2024131870 title "Preparation and characterization of dinuclear copper–indomethacin anti-inflammatory drugs" @default.
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• W2024131870 doi "https://doi.org/10.1016/s0020-1693(01)00570-9" @default.
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