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- W2024132308 abstract "The main applications of water-soluble polymers in the oil industry, i.e. polymer flooding and water-based drilling muds, require water-soluble polymers to be compatible with corrodible materials. With this aim, the behavior of polyacrylamides and xanthans in the presence of various materials used for oil production (e.g. steel, stainless steel, carbon steel, Inconel) has been studied at different water salinities, oxygen contents and temperatures. The influence of commonly used additives such as oxygen scavengers and sequestrants on corrosion and polymer stability has also been investigated. For both types of polymer, as corrosion occurs, under anaerobic conditions, strong interactions between charged groups of polymer chains and divalent cations formed, such as Fe(II) or Ni(II), lead to a decrease in solution viscosity. A strong influence of the presence of impurities on polymer behavior has been observed. In the presence of oxygen, corrosion induces a molecular weight degradation of the polymer followed by a gelation process in some cases, specially for xanthan. Additives such as sequestrants may accelerate the transformation of Fe(II) to Fe(III), and subsequent polymer degradation, but this reaction depends on the nature of the chelating agent. These results provide guidelines for the use of polymers in oil production, including the selection of materials, products for water treatment or mud formulation." @default.
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- W2024132308 title "Stability of water-soluble polymers in the presence of corrodible materials" @default.
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- W2024132308 doi "https://doi.org/10.1016/0141-3910(93)90207-y" @default.
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