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- W2024143800 endingPage "3039" @default.
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- W2024143800 abstract "A rhodium-catalyzed asymmetric synthesis of β-lactones via intramolecular C–H insertion into the ester group of aryldiazoacetates has been developed. The β-lactones were synthesized in high yields and with high levels of diastereo- and enantioselectivity. Halo and trifluoromethyl substituents at the ortho position of the aryldiazoacetates enhance intramolecular C–H insertions over intermolecular reactions, allowing C–H insertion of even methyl C–H bonds." @default.
- W2024143800 created "2016-06-24" @default.
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- W2024143800 date "2014-05-20" @default.
- W2024143800 modified "2023-10-14" @default.
- W2024143800 title "Role of <i>Ortho</i>-Substituents on Rhodium-Catalyzed Asymmetric Synthesis of β-Lactones by Intramolecular C–H Insertions of Aryldiazoacetates" @default.
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- W2024143800 doi "https://doi.org/10.1021/ol5011505" @default.
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