Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024164267> ?p ?o ?g. }
- W2024164267 endingPage "901" @default.
- W2024164267 startingPage "901" @default.
- W2024164267 abstract "Here we report the homogeneously-catalyzed etherification of glycerol with short chain alkyl alcohols. Among the large variety of Brønsted and Lewis acids tested, we show here that metal triflates are not only the most active but are also capable of catalyzing this reaction with an unprecedented selectivity. In particular, in the presence of Bi(OTf)3, the targeted monoalkylglyceryl ethers were obtained with up to 70% yield. Although tested Brønsted acids were also capable of catalyzing the etherification of glycerol with alkyl alcohols, they were found however less active and less selective than Bi(OTf)3. By means of counter experiments, we highlighted that the high activity and selectivity of Bi(OTf)3 may rely on a synergistic effect between Bi(OTf)3 and triflic acid, a Brønsted acid that can be released by in situ glycerolysis of Bi(OTf)3. The scope of this methodology was also extended to other polyols and, in all cases, the monoalkylpolyol ethers were conveniently obtained with fair to good yields." @default.
- W2024164267 created "2016-06-24" @default.
- W2024164267 creator A5007919320 @default.
- W2024164267 creator A5015060787 @default.
- W2024164267 creator A5038231602 @default.
- W2024164267 creator A5048279362 @default.
- W2024164267 creator A5070971453 @default.
- W2024164267 creator A5073632701 @default.
- W2024164267 creator A5086059562 @default.
- W2024164267 date "2013-01-01" @default.
- W2024164267 modified "2023-10-10" @default.
- W2024164267 title "Catalytic etherification of glycerol with short chain alkyl alcohols in the presence of Lewis acids" @default.
- W2024164267 cites W1967410318 @default.
- W2024164267 cites W1983420407 @default.
- W2024164267 cites W1985069924 @default.
- W2024164267 cites W1998321859 @default.
- W2024164267 cites W1998714557 @default.
- W2024164267 cites W2002529545 @default.
- W2024164267 cites W2005428145 @default.
- W2024164267 cites W2009482922 @default.
- W2024164267 cites W2026872956 @default.
- W2024164267 cites W2033374581 @default.
- W2024164267 cites W2037884103 @default.
- W2024164267 cites W2040436974 @default.
- W2024164267 cites W2051732106 @default.
- W2024164267 cites W2063710075 @default.
- W2024164267 cites W2064710718 @default.
- W2024164267 cites W2076192137 @default.
- W2024164267 cites W2078371719 @default.
- W2024164267 cites W2080850737 @default.
- W2024164267 cites W2088609625 @default.
- W2024164267 cites W2089410804 @default.
- W2024164267 cites W2094602756 @default.
- W2024164267 cites W2098704057 @default.
- W2024164267 cites W2104745127 @default.
- W2024164267 cites W2111674694 @default.
- W2024164267 cites W2115785832 @default.
- W2024164267 cites W2121654594 @default.
- W2024164267 cites W2132019923 @default.
- W2024164267 cites W2135311979 @default.
- W2024164267 cites W2141773818 @default.
- W2024164267 cites W2144184220 @default.
- W2024164267 cites W2144189707 @default.
- W2024164267 cites W2150169893 @default.
- W2024164267 cites W2152819526 @default.
- W2024164267 cites W2157073452 @default.
- W2024164267 cites W2159902970 @default.
- W2024164267 cites W2166550852 @default.
- W2024164267 cites W2169709967 @default.
- W2024164267 cites W2175496259 @default.
- W2024164267 cites W2326266449 @default.
- W2024164267 cites W28734554 @default.
- W2024164267 doi "https://doi.org/10.1039/c3gc36944g" @default.
- W2024164267 hasPublicationYear "2013" @default.
- W2024164267 type Work @default.
- W2024164267 sameAs 2024164267 @default.
- W2024164267 citedByCount "55" @default.
- W2024164267 countsByYear W20241642672013 @default.
- W2024164267 countsByYear W20241642672014 @default.
- W2024164267 countsByYear W20241642672015 @default.
- W2024164267 countsByYear W20241642672016 @default.
- W2024164267 countsByYear W20241642672017 @default.
- W2024164267 countsByYear W20241642672018 @default.
- W2024164267 countsByYear W20241642672019 @default.
- W2024164267 countsByYear W20241642672020 @default.
- W2024164267 countsByYear W20241642672021 @default.
- W2024164267 countsByYear W20241642672022 @default.
- W2024164267 countsByYear W20241642672023 @default.
- W2024164267 crossrefType "journal-article" @default.
- W2024164267 hasAuthorship W2024164267A5007919320 @default.
- W2024164267 hasAuthorship W2024164267A5015060787 @default.
- W2024164267 hasAuthorship W2024164267A5038231602 @default.
- W2024164267 hasAuthorship W2024164267A5048279362 @default.
- W2024164267 hasAuthorship W2024164267A5070971453 @default.
- W2024164267 hasAuthorship W2024164267A5073632701 @default.
- W2024164267 hasAuthorship W2024164267A5086059562 @default.
- W2024164267 hasBestOaLocation W20241642672 @default.
- W2024164267 hasConcept C118792377 @default.
- W2024164267 hasConcept C134121241 @default.
- W2024164267 hasConcept C161790260 @default.
- W2024164267 hasConcept C163638829 @default.
- W2024164267 hasConcept C178790620 @default.
- W2024164267 hasConcept C185592680 @default.
- W2024164267 hasConcept C191897082 @default.
- W2024164267 hasConcept C192562407 @default.
- W2024164267 hasConcept C21951064 @default.
- W2024164267 hasConcept C2779128551 @default.
- W2024164267 hasConcept C2780263894 @default.
- W2024164267 hasConcept C2780881558 @default.
- W2024164267 hasConcept C79878483 @default.
- W2024164267 hasConceptScore W2024164267C118792377 @default.
- W2024164267 hasConceptScore W2024164267C134121241 @default.
- W2024164267 hasConceptScore W2024164267C161790260 @default.
- W2024164267 hasConceptScore W2024164267C163638829 @default.
- W2024164267 hasConceptScore W2024164267C178790620 @default.
- W2024164267 hasConceptScore W2024164267C185592680 @default.
- W2024164267 hasConceptScore W2024164267C191897082 @default.
- W2024164267 hasConceptScore W2024164267C192562407 @default.