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• W2024165784 abstract "The ultrafast production and decay of carbenes from the diphenyldiazomethane precursor in isooctane has been investigated by femtosecond transient absorption spectroscopy. Diphenylcarbene is produced in less than 300 fs in a singlet state. It then undergoes an ultrafast (∼300 fs) internal conversion followed by an intermediate step of a few picoseconds, which we attribute to a conformational change between its C1 and C2v geometries. Finally, intersystem crossing from S1 to the triplet ground state occurs in ∼100 ps." @default.
• W2024165784 created "2016-06-24" @default.
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• W2024165784 date "1998-11-01" @default.
• W2024165784 modified "2023-09-25" @default.
• W2024165784 title "Femtosecond study of the rise and decay of carbenes in solution" @default.
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• W2024165784 doi "https://doi.org/10.1016/s0009-2614(98)01057-4" @default.
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