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- W2024167772 abstract "Abstract The regio- and stereoselectivity of the reaction between PhSeCl and PhSCl and a number of 7-oxabicyclo[2.2.1]hept-5-enes bearing an oxygenated substituent on C-2 is discussed. In most cases, both electrophiles react with complete regio- and stereoselectivity to provide 5-endo-chloro- 6-exo-benzeneselenenyl (benzenesulfenyl) derivatives. 7-Oxanorbornen- 2-endo-ols behave differently with both electrophiles. Thus, while PhSeCl produces 5-endo-chloro-6-exo-benzeneselenenyl adducts and small amounts of 4,7- dioxatricyclo[3.2.1.03.6]octane derivatives, PhSCl affords a good yield of 5-exo-methyl-2-exo-phenylsulfenyl-4,7-dioxatricyclo [3.2.1.03,6]octane." @default.
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- W2024167772 date "1989-01-01" @default.
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- W2024167772 title "Regioselective electrophilic additions to 2-oxygenated-7-oxabicyclo[2.2.1]Hept-5-enes: A simple entry into the 4,7-dioxatricyclo[3.2.1.03,6]octaneskeleton" @default.
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- W2024167772 doi "https://doi.org/10.1016/s0040-4020(01)89091-8" @default.
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