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- W2024170242 abstract "Dioxygen (O2) activation by iron enzymes is responsible for many metabolically important transformations in biology. Often a high-valent iron oxo oxidant is proposed to form upon O2 activation at a mononuclear nonheme iron center, presumably via intervening iron superoxo and iron peroxo species. While iron(IV) oxo intermediates have been trapped and characterized in enzymes and models, less is known of the putative iron(III) superoxo species. Utilizing a synthetic model for the 2-oxoglutarate-dependent monoiron enzymes, [(TpiPr2)FeII(O2CC(O)CH3)], we have obtained indirect evidence for the formation of the putative iron(III) superoxo species, which can undergo one-electron reduction, hydrogen-atom transfer, or conversion to an iron(IV) oxo species, depending on the reaction conditions. These results demonstrate the various roles that the iron(III) superoxo species can play in the course of O2 activation at a nonheme iron center." @default.
- W2024170242 created "2016-06-24" @default.
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- W2024170242 date "2010-04-12" @default.
- W2024170242 modified "2023-10-16" @default.
- W2024170242 title "Oxygen Activation at Mononuclear Nonheme Iron Centers: A Superoxo Perspective" @default.
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- W2024170242 cites W1966856386 @default.
- W2024170242 cites W1967700647 @default.
- W2024170242 cites W1968809123 @default.
- W2024170242 cites W1969474820 @default.
- W2024170242 cites W1972575681 @default.
- W2024170242 cites W1984531703 @default.
- W2024170242 cites W1988949059 @default.
- W2024170242 cites W1999251677 @default.
- W2024170242 cites W1999698862 @default.
- W2024170242 cites W2002343231 @default.
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- W2024170242 cites W2007742038 @default.
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- W2024170242 cites W2009050720 @default.
- W2024170242 cites W2010496954 @default.
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- W2024170242 cites W2013276272 @default.
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- W2024170242 doi "https://doi.org/10.1021/ic901891n" @default.
- W2024170242 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2864595" @default.
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