FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024174670> ?p ?o ?g. }

• W2024174670 endingPage "3315" @default.
• W2024174670 startingPage "3310" @default.
• W2024174670 abstract "Reaction of NO with the iron complex of N-(dithiocarboxy)sarcosine (H2DTCS) was investigated by UV/VIS absorption spectroscopy, HPLC, LC-ESI MS and pulse radiolysis. The results of HPLC and LC-ESI MS clearly showed that the reaction products of NO with [FeIII(DTCS)3]3− are [NO–FeII(DTCS)2]2− and a dimer of DTCS in which two DTCS bind through a disulfide bond. On pulse radiolysis of a deaerated aqueous solution of [FeIII(DTCS)3]3− in the presence of sodium nitrite the absorption changes consisted of three phases, as judged from kinetic difference spectra. In the faster phase, radiolytically generated NO reacted with [FeIII(DTCS)3]3− to form a transient intermediate I with a second-order rate constant of (4.8 ± 0.9) × 108 dm3 mol−1 s−1. Subsequently, I reacted with unchanged [FeIII(DTCS)3]3− to give an intermediate II with an absorption maximum at 460 nm. In the third step II was found to decay on a timescale of seconds. The final product in the sequence of the reactions was [NO–FeII(DTCS)2]2−. From the spectra obtained, the intermediate II is discussed in relation to the iron(IV) complex of N,N-diethyldithiocarbamate. These results suggest that the proposed reaction mechanism is a new type of reductive nitrosylation involving iron(IV) as an intermediate." @default.
• W2024174670 created "2016-06-24" @default.
• W2024174670 creator A5038517671 @default.
• W2024174670 creator A5074322711 @default.
• W2024174670 creator A5074819917 @default.
• W2024174670 creator A5080530083 @default.
• W2024174670 date "2000-01-01" @default.
• W2024174670 modified "2023-09-28" @default.
• W2024174670 title "Reaction of nitric oxide with the iron(III) complex of N-(dithiocarboxy)sarcosine: a new type of reductive nitrosylation involving iron(IV) as an intermediate †" @default.
• W2024174670 cites W118855494 @default.
• W2024174670 cites W1970892728 @default.
• W2024174670 cites W1976271098 @default.
• W2024174670 cites W1978816776 @default.
• W2024174670 cites W1987166207 @default.
• W2024174670 cites W1989943872 @default.
• W2024174670 cites W1991329566 @default.
• W2024174670 cites W1991384716 @default.
• W2024174670 cites W1991984561 @default.
• W2024174670 cites W1997439028 @default.
• W2024174670 cites W2008862844 @default.
• W2024174670 cites W2009141141 @default.
• W2024174670 cites W2011470758 @default.
• W2024174670 cites W2019435702 @default.
• W2024174670 cites W2024743469 @default.
• W2024174670 cites W2029067920 @default.
• W2024174670 cites W2031609968 @default.
• W2024174670 cites W2032000242 @default.
• W2024174670 cites W2039831515 @default.
• W2024174670 cites W2041385810 @default.
• W2024174670 cites W2042358124 @default.
• W2024174670 cites W2054206173 @default.
• W2024174670 cites W2056100625 @default.
• W2024174670 cites W2062316787 @default.
• W2024174670 cites W2064872190 @default.
• W2024174670 cites W2067493659 @default.
• W2024174670 cites W2067590620 @default.
• W2024174670 cites W2069347285 @default.
• W2024174670 cites W2075049158 @default.
• W2024174670 cites W2076043812 @default.
• W2024174670 cites W2082964670 @default.
• W2024174670 cites W2084227614 @default.
• W2024174670 cites W2091775196 @default.
• W2024174670 cites W2092739580 @default.
• W2024174670 cites W2093090693 @default.
• W2024174670 cites W2152046668 @default.
• W2024174670 cites W2160969790 @default.
• W2024174670 cites W2326282712 @default.
• W2024174670 cites W2330632781 @default.
• W2024174670 cites W2333089555 @default.
• W2024174670 cites W2342414629 @default.
• W2024174670 cites W2950011019 @default.
• W2024174670 cites W2950369001 @default.
• W2024174670 cites W3005457560 @default.
• W2024174670 cites W3137461126 @default.
• W2024174670 cites W3143062639 @default.
• W2024174670 cites W64990613 @default.
• W2024174670 doi "https://doi.org/10.1039/b003942j" @default.
• W2024174670 hasPublicationYear "2000" @default.
• W2024174670 type Work @default.
• W2024174670 sameAs 2024174670 @default.
• W2024174670 citedByCount "31" @default.
• W2024174670 countsByYear W20241746702012 @default.
• W2024174670 countsByYear W20241746702016 @default.
• W2024174670 countsByYear W20241746702017 @default.
• W2024174670 countsByYear W20241746702019 @default.
• W2024174670 countsByYear W20241746702021 @default.
• W2024174670 crossrefType "journal-article" @default.
• W2024174670 hasAuthorship W2024174670A5038517671 @default.
• W2024174670 hasAuthorship W2024174670A5074322711 @default.
• W2024174670 hasAuthorship W2024174670A5074819917 @default.
• W2024174670 hasAuthorship W2024174670A5080530083 @default.
• W2024174670 hasConcept C119824511 @default.
• W2024174670 hasConcept C121332964 @default.
• W2024174670 hasConcept C139066938 @default.
• W2024174670 hasConcept C13965031 @default.
• W2024174670 hasConcept C147789679 @default.
• W2024174670 hasConcept C148898269 @default.
• W2024174670 hasConcept C155647269 @default.
• W2024174670 hasConcept C178790620 @default.
• W2024174670 hasConcept C179104552 @default.
• W2024174670 hasConcept C184651966 @default.
• W2024174670 hasConcept C185592680 @default.
• W2024174670 hasConcept C2776179834 @default.
• W2024174670 hasConcept C2776384668 @default.
• W2024174670 hasConcept C2777756961 @default.
• W2024174670 hasConcept C2779943223 @default.
• W2024174670 hasConcept C45068187 @default.
• W2024174670 hasConcept C515207424 @default.
• W2024174670 hasConcept C519581460 @default.
• W2024174670 hasConcept C55493867 @default.
• W2024174670 hasConcept C62520636 @default.
• W2024174670 hasConcept C66887884 @default.
• W2024174670 hasConcept C75473681 @default.
• W2024174670 hasConcept C93391505 @default.
• W2024174670 hasConceptScore W2024174670C119824511 @default.
• W2024174670 hasConceptScore W2024174670C121332964 @default.
• W2024174670 hasConceptScore W2024174670C139066938 @default.
• W2024174670 hasConceptScore W2024174670C13965031 @default.

• next