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• W2024175021 startingPage "732" @default.
• W2024175021 abstract "Abstract The development of a new surface architecture for the efficient direct electron transfer of positively charged redox proteins is presented. For this reason different kinds of polyaniline terpolymers consisting of aminobenzoic acid (AB), aminobenzenesulfonic acid (ABS) and aniline (A) with different monomer ratios were synthesized. The P(AB‐ABS‐A) were grafted to the surface of multiwalled carbon nanotubes (MWCNTs). FTIR measurements prove the covalent binding to the carboxylic groups of the MWCNTs while conductivity tests show an increase in the conductivity of the nanohybrid in comparison to the polymers. The [MWCNT‐P(AB‐ABS‐A)] nanohybrids were used for the immobilization of redox active cytochrome c (cyt.c). The positively charged protein can electrostatically interact with the negatively charged nanohybrid. Cyclic voltammetry (CV) shows an increase in the protein loading on [MWCNT‐P(AB‐ABS‐A)] coupled to cysteamine modified gold electrodes in comparison to non‐grafted MWCNTs. A further increase in the sulfonation degree of P(AB‐ABS‐A) leads to an enhanced current output of the modified electrodes. The redox activity of the polymer decreases after the immobilization of the cyt.c on the nanohybrid. For the first time polymers covalently grafted to the surface of MWCNTs are used in a biosensor." @default.
• W2024175021 created "2016-06-24" @default.
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• W2024175021 date "2014-03-18" @default.
• W2024175021 modified "2023-10-16" @default.
• W2024175021 title "Nanohybrid Materials Consisting of Poly[(3-aminobenzoic acid)-co-(3-aminobenzenesulfonic acid)-co-aniline] and Multiwalled Carbon Nanotubes for Immobilization of Redox Active Cytochrome c" @default.
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• W2024175021 doi "https://doi.org/10.1002/elan.201300526" @default.
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