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- W2024186994 abstract "Abstract Dispersed phosphorescence and phosphorescence excitation spectra were obtained for gas-phase methyl benzoate. Relative phosphorescence quantum yields for methyl, ethyl, and n -butyl benzoate were determined for five excitation energies above the 0,0 band and of the second 1 (π, π*) transition. The emitting state was assigned as the 3 (n, π*) state. Relative phosphorescence yields were found to be inconsistent with trends expected for variation in either intersystem crossing rates or photodissociation rates as a function of alkyl chain length, strongly suggesting a competing molecular elimination process." @default.
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- W2024186994 date "1992-07-01" @default.
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- W2024186994 title "Molecular structure effects on carbonyl photophysics: phosphorescence yields for n-alkyl benzoate esters" @default.
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- W2024186994 doi "https://doi.org/10.1016/0009-2614(92)85564-q" @default.
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