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- W2024216955 startingPage "1325" @default.
- W2024216955 abstract "In the $mathrm{H}(g)ensuremath{-}mathrm{on}ensuremath{-}{mathrm{D}}_{mathrm{ad}}$ abstraction reaction on a Pt(111) surface at 100 K, HD molecules are formed via direct Eley-Rideal and primary hot atom mechanisms as well as via a secondary hot atom mechanism with an equal yield but distinctively different kinetics and angular distributions peaked at $ensuremath{sim}0ifmmode^circelsetextdegreefi{}$ and $ensuremath{sim}45ifmmode^circelsetextdegreefi{}$ from the surface normal, respectively. However, the former two mechanisms are not distinguished in the present experiment. About 37% of adsorbed D atoms desorbed as ${mathrm{D}}_{2}$ formed via a secondary hot atom mechanism with a distribution also peaked at $ensuremath{sim}45ifmmode^circelsetextdegreefi{}$. Results are discussed in terms of the reaction dynamics." @default.
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- W2024216955 date "1999-02-08" @default.
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- W2024216955 title "Spatial and Kinetic Separation of Eley-Rideal Plus Primary Hot Atom and Secondary Hot Atom Mechanisms in H Atom Abstraction of Adsorbed D Atoms on Pt(111)" @default.
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- W2024216955 doi "https://doi.org/10.1103/physrevlett.82.1325" @default.
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